If you mean PSN's Achievement system, I don't think so unless that works offline (does it? I don't own a PS3). I reckon trying to go online with an emulator would be as easily detected as trying to do that with a jailbroken PS3.
And even if it does work offline, I don't know to which point PSN features implementation is possible/practical.
And even if it does work offline, I don't know to which point PSN features implementation is possible/practical.
My Rig:
OS: Windows 7 Professional 64bit SP1
CPU: AMD Phenom II X4 955 3.2 GHz Stock
Graphics Card: Nvidia GeForce GTX 560 1GB GDDR5
Motherboard: Gigabyte GA-870A-USB3 AM3+ Revision
RAM: Geil 4GB Dual Channel @ 1600Mhz